{"id":4925,"date":"2022-07-14T10:04:32","date_gmt":"2022-07-14T02:04:32","guid":{"rendered":"https:\/\/www.51dmea.cn\/?p=4925"},"modified":"2022-07-14T10:10:46","modified_gmt":"2022-07-14T02:10:46","slug":"%e5%87%a0%e4%b8%aa%e9%87%8d%e8%a6%81%e8%8d%af%e7%89%a9%e4%b8%ad%e9%97%b4%e4%bd%93%e7%9a%84%e5%b8%82%e5%9c%ba%e5%89%8d%e6%99%af%e5%88%86%e6%9e%90","status":"publish","type":"post","link":"https:\/\/www.51dmea.cn\/archives\/4925","title":{"rendered":"\u51e0\u4e2a\u91cd\u8981\u836f\u7269\u4e2d\u95f4\u4f53\u7684\u5e02\u573a\u524d\u666f\u5206\u6790"},"content":{"rendered":"

\u51e0\u4e2a\u91cd\u8981\u836f\u7269\u4e2d\u95f4\u4f53<\/a>\u7684\u5e02\u573a\u524d\u666f\u5206\u6790<\/b><\/strong><\/span><\/p>\n

\u533b\u836f\u4f5c\u4e3a\u7cbe\u7ec6\u5316\u5de5\u9886\u57df\u4e2d\u91cd\u8981\u5730\u884c\u4e1a,\u6210\u4e3a\u8fd1\u5341\u5e74\u6765\u53d1\u5c55\u4e0e\u7ade\u4e89\u5730\u7126\u70b9,\u968f\u7740\u79d1\u5b66\u6280\u672f\u5730\u8fdb\u6b65,\u8bb8\u591a\u533b\u836f\u88ab\u6e90\u6e90\u4e0d\u65ad\u5730\u5f00\u53d1\u51fa\u6765,\u9020\u798f\u4eba\u7c7b,\u8fd9\u4e9b\u533b\u836f\u5730\u5408\u6210\u4f9d\u8d56\u4e8e\u65b0\u578b\u5730\u9ad8\u8d28\u91cf\u5730\u533b\u836f\u4e2d\u95f4\u4f53\u5730\u751f\u4ea7,\u65b0\u836f\u53d7\u5230\u4e13\u5229\u4fdd\u62a4,\u800c\u4e0e\u4e4b\u914d\u5957\u5730\u4e2d\u95f4\u4f53\u5374\u4e0d\u5b58\u5728\u90a3\u6837\u5730\u95ee\u9898,\u56e0\u6b64\u65b0\u578b\u533b\u836f\u4e2d\u95f4\u4f53\u56fd\u5185\u5916\u5e02\u573a\u548c\u5e94\u7528\u524d\u666f\u90fd\u5341\u5206\u770b\u597d.\u65b0\u578b\u533b\u836f\u4e2d\u95f4\u4f53\u54c1\u79cd\u4f17\u591a,\u4e0d\u53ef\u80fd\u5b8c\u5168\u4ecb\u7ecd,\u672c\u6587\u7b80\u8981\u4ecb\u7ecd\u8fd1\u5e74\u6765\u56fd\u5185\u5f00\u59cb\u7814\u7a76\u3001\u975e\u5e38\u503c\u5f97\u5173\u6ce8\u5730\u65b0\u578b\u5730\u533b\u836f\u4e2d\u95f4\u4f53\u53ca\u4e00\u4e9b\u91cd\u8981\u533b\u836f\u4e2d\u95f4\u4f53\u5730\u65b0\u5de5\u827a.<\/span><\/p>\n

$\"\"$ <\/p>\n

1\u30011-(6-\u7532\u6c27\u57fa-2-\u8418\u57fa)<\/b><\/strong><\/span><\/p>\n

\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u975e\u753e\u4f53\u6d88\u708e\u836f\u7269\u8418\u666e\u751f\u6709\u591a\u79cd\u5408\u6210\u65b9\u6cd5,\u5176\u4e2d\u7fb0\u57fa\u5316\u5408\u6210\u8def\u7ebf\u5730\u9ad8\u9009\u62e9\u6027\u3001\u73af\u5883\u53cb\u597d\u6027,\u4f7f\u5f97\u7fb0\u57fa\u5316\u5408\u6210\u5730\u975e\u753e\u4f53\u6d88\u708e\u836f\u4f18\u4e8e\u4f20\u7edf\u5730\u8def\u7ebf.\u7fb0\u57fa\u5316\u5408\u6210\u8418\u666e\u751f\u5730\u5173\u952e\u4e2d\u95f4\u4f53\u5c31\u662f1-(6-\u7532\u6c27\u57fa-2-\u8418\u57fa).\u56fd\u5185\u6e56\u5357\u5927\u5b66\u4ee52-\u7532\u6c27\u57fa\u8418\u4e3a\u539f\u6599,\u91c7\u75281,3-\u4e8c\u6eb4-5,5-\u4e8c\u7532\u57fa\u4e59\u5185\u9170\u8132\u76d0\u9178\u50ac\u5316\u6eb4\u4e59\u9170\u57fa\u5316\u3001\u4e59\u9170\u57fa\u5316\u548c\u5e38\u538b\u4e0b\u94af\u591a\u76f8\u50ac\u5316\u52a0\u6c22\u8fd8\u539f,\u7ecf\u8fc71-\u6eb4-2-\u7532\u6c27\u57fa\u8418\u30015-\u6eb4-6-\u7532\u6c27\u57fa-2-\u4e59\u9170\u57fa\u8418\u7b49\u4e2d\u95f4\u4ea7\u7269\u7ec8\u5f97\u5230\u4ea7\u54c1\u3002<\/span><\/p>\n

2<\/b><\/strong>\u3001\u03b1-\u4e9a\u7532\u57fa\u73af\u916e<\/b><\/strong><\/span><\/p>\n

\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u03b1-\u4e9a\u7532\u57fa\u73af\u916e\u662f\u8bb8\u591a\u5177\u6709\u6297\u764c\u6d3b\u6027\u836f\u7269\u5730\u6d3b\u6027\u4e2d\u5fc3,\u5176\u542b\u6709\u03b1,\u03b2-\u4e0d\u9971\u548c\u916e\u7ed3\u6784\u5c5e\u4e8e\u6297\u764c\u6d3b\u6027\u57fa\u56e2\u5730\u9690\u853d\u57fa\u56e2,\u6210\u4e3a\u5408\u6210\u5f88\u591a\u91cd\u8981\u73af\u72b6\u6297\u764c\u836f\u7269\u5730\u91cd\u8981\u4e2d\u95f4\u4f53.\u6587\u732e\u62a5\u9053\u5408\u6210\u8def\u7ebf\u6709\u4e09,1)\u662f\u73af\u916e\u548c\u7532\u919b\u5730\u7f9f\u919b\u7f29\u5408;2)\u7531Mannich\u53cd\u5e94\u4ea7\u751f\u03b2-\u4e8c\u70f7\u57fa\u80fa\u7532\u57fa\u73af\u916e,\u4ea7\u7269\u80fa\u6216\u5b63\u94f5\u76d0\u5730\u70ed\u5206\u89e3\u4ea7\u751f\u03b1-\u4e9a\u7532\u57fa\u73af\u916e;3)\u662f\u73af\u916e\u4e0e\u8349\u9178\u4e8c\u4e59\u916f\u7f29\u5408\u540e,\u4e0e\u7532\u919b\u53cd\u5e94\u5f97\u5230\u03b1-\u4e9a\u7532\u57fa\u73af\u916e.\u56fd\u5185\u4e2d\u79d1\u9662\u5e7f\u5dde\u836f\u7269\u7814\u7a76\u6240\u5f00\u53d1\u51fa\u5206\u522b\u4ee5\u73af\u620a\u916e\u3001\u73af\u5df2\u916e\u3001\u5f02\u4f5b\u5c14\u916e\u5206\u522b\u4e0e\u8349\u9178\u4e8c\u4e59\u916f\u53cd\u5e94\u540e,\u53cd\u5e94\u4ea7\u7269\u518d\u4e0e\u7532\u919b\u4e00\u8d77\u53cd\u5e94\u5f97\u5230\u76f8\u5e94\u5730\u03b1-\u4e9a\u7532\u57fa\u73af\u620a\u916e\u3001\u03b1-\u4e9a\u7532\u57fa\u73af\u5df2\u916e\u548c\u03b1-\u4e9a\u7532\u57fa\u5f02\u4f5b\u5c14\u916e\u7b49.\u5176\u4e2d\u7b2c\u4e00\u6b65\u8981\u5728\u6eb6\u5242\u5b58\u5728\u4e0b\u53cd\u5e94,\u6eb6\u5242\u4e00\u822c\u9009\u7528\u4e8c\u7532\u57fa\u4e9a\u781c\u548c\u56db\u6c22\u544b\u5583\u7b49.<\/span><\/p>\n

3<\/b><\/strong>\u30014,4′-\u4e8c\u7532\u6c27\u57fa\u4e59\u9170\u7532\u916f<\/b><\/strong><\/span><\/p>\n

\u00a0\u00a0\u00a0\u00a0\u00a0\u00a04,4′-\u4e8c\u7532\u6c27\u57fa\u4e59\u9170\u7532\u916f\u662f\u91cd\u8981\u5730\u5fc3\u8111\u8840\u7ba1\u75be\u75c5\u6cbb\u7597\u836f\u7269\u5c3c\u4f10\u5730\u5e73\u5730\u4e2d\u95f4\u4f53,\u5c3c\u4f10\u5730\u5e73\u662f\u7531\u65e5\u672c\u85e4\u6cfd\u836f\u54c1\u516c\u53f8\u5f00\u53d1,1989\u5e74\u4e0a\u5e02\u5730\u7b2c\u4e8c\u4ee3\u9499\u62ee\u6297\u5242,\u662f\u76ee\u524d\u56fd\u9645\u5e02\u573a\u4e0a\u4e3b\u5bfc\u5730\u5fc3\u8111\u8840\u7ba1\u75be\u75c5\u6cbb\u7597\u836f\u7269,\u56fd\u5185\u5c1a\u6ca1\u6709\u751f\u4ea7.\u4ee5\u4e59\u919b\u9178\u4e3a\u539f\u6599\u4e0e\u539f\u7532\u9178\u4e09\u7532\u916f\u5728\u6d53\u5b58\u5728\u4e0b\u5408<\/span><\/p>\n

\u6210\u5f97\u5230\u4e8c\u7532\u6c27\u57fa\u7532\u916f,\u540e\u8005\u4e0e\u7532\u916f\u3001\u7532\u9187\u94a0\u53cd\u5e94\u5f97\u52304,4′-\u4e8c\u7532\u6c27\u57fa\u4e59\u9170\u7532\u916f.<\/span><\/p>\n

4<\/b><\/strong>\u3001C3-\u6c2f\u4ee3\u5934\u5b62\u70ef\u9178<\/b><\/strong><\/span><\/p>\n

\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0C3-\u6c2f\u4ee3\u5934\u5b62\u70ef\u9178\u662f\u91cd\u8981\u5934\u5b62\u83cc\u7d20\u5934\u5b62\u514b\u6d1b\u4e2d\u95f4\u4f53,\u5934\u5b62\u514b\u6d1b\u662f\u7531\u7f8e\u56fd\u793c\u83b1\u516c\u53f8\u5f00\u53d1\u5730\u7b2c\u4e8c\u4ee3\u9ad8\u6548\u53e3\u670d\u5934\u5b62\u83cc\u7d20,\u7531\u4e8e\u5176\u7597\u6548\u660e\u663e\u53ca\u53e3\u670d\u4f18\u52bf,2001\u5e74\u5728\u7f8e\u56fd\u9500\u552e\u989d\u8fbe\u52308000\u4e07\u5143\u4ee5\u4e0a,\u4f4d\u5c45\u6297\u751f\u7d20\u836f\u7269\u7b2c\u4e8c.C3-\u6c2f\u4ee3\u5934\u5b62\u70ef\u9178\u5408\u6210\u8def\u7ebf\u6709\u4e24\u79cd,1)\u662f\u9752\u9709\u7d20G\u76d0\u7ecf\u8fc7\u6c27\u5316\u3001\u916f\u5316\u3001\u6269\u73af\u3001\u8fd8\u539f\u3001\u6c27\u5316\u3001\u8fd8\u539f\u3001\u6c27\u5316\u3001\u53bb\u4e59\u9170\u57fa\u3001\u6c34\u89e3\u7b49\u591a\u6b65\u5408\u6210,\u6b65\u9aa4\u592a\u591a,\u6536\u7387\u4f4e;2)\u662f\u4ee57-\u6c28\u57fa\u5934\u5b62\u70f7\u9178(7-ACA)\u4e3a\u539f\u6599,7-ACA \u5728\u8fdb\u884c3-\u4f4d\u5730\u6bcd\u6838\u6539\u9020\u65f6,\u7531\u4e8e\u51767-\u4f4d\u6c28\u57fa\u548c4-\u4f4d\u7fa7\u57fa\u6d3b\u6027\u5f88\u9ad8,\u9996\u5148\u8981\u8fdb\u884c\u4fdd\u62a4,4-\u7fa7\u57fa\u4fdd\u62a4\u5e38\u7528\u65b9\u6cd5\u5c06\u5176\u5236\u6210\u53d4\u4e01\u916f\u3001\u4e8c\u7532\u916f\u548c\u5bf9\u785d\u57fa\u82c4\u916f;7-\u6c28\u57fa\u5730\u4fdd\u62a4\u53ef\u91c7\u7528\u6c27\u7532\u57fa\u3001\u82c4\u57fa\u3001\u4ee5\u53ca\u4e09\u7532\u57fa\u6c2f\u7532\u7845\u70f7\u7b49\u7532\u7845\u70f7\u57fa\u5316\u8bd5\u5242\u4fdd\u62a4.\u7136\u540e\u8fdb\u884c\u4eb2\u6838\u53d6\u4ee3\u548c\u8fd8\u539f\u53cd\u5e94,\u9996\u5148\u901a\u8fc7\u542b\u786b\u5730\u4eb2\u6838\u8bd5\u5242,\u5982\u4e59\u57fa\u9ec4\u539f\u9178\u76d0\u3001\u786b\u8132\u6216\u786b\u9187\u5bf9\u5934\u5b62\u70f7\u9178\u8fdb\u884c\u4eb2\u6838\u53d6\u4ee3\u4e59\u6c27\u57fa\u56e2,\u518d\u7528\u954d\u4e3a\u50ac\u5316\u5242\u6c22\u5316\u8fd8\u539f\u751f\u62103-\u73af\u5916\u4e9a\u7532\u57fa\u5934\u5b62\u70f7\u9178;\u7136\u540e\u8fdb\u884c\u73af\u5916\u53cc\u952e\u5730\u6c27\u5316\u53ca\u8fd8\u539f,\u6c27\u5316\u5242\u4e00\u822c\u9009\u7528\u81ed\u6c27,\u5176\u4e2d\u5173\u952e\u8981\u63a7\u5236\u6c27\u5316\u6df1\u5ea6,\u5e38\u7528\u8fd8\u539f\u5242\u6709\u4e9a\u6c22\u76d0\u3001\u4e8c\u7532\u786b\u919a\u3001\u4e8c\u6c27\u5316\u786b\u53ca\u4e09\u7532\u57fa\u78f7\u9178\u76d0\u7b49;\u7b2c\u4e09\u6b65\u662f\u6c2f\u4ee3\u3001\u8131\u4fdd\u62a4\u57fa\u53ca\u6c34\u89e3\u53cd\u5e94,\u6c2f\u5316\u5242\u53ef\u9009\u7528SOCl2\u3001PCl3\u3001POCl3\u3001COCl3\u6216\u56fa\u4f53\u5149\u6c14\u7b49,\u53ef\u4ee5\u6c2f\u4ee3\u3001\u8131\u9170\u3001\u6c34\u89e3\u4e00\u6b65\u5b8c\u6210\u5f97\u5230C3l\u6c2f\u4ee3\u5934\u5b62\u70ef\u9178\u6bcd\u6838.<\/span><\/p>\n

$\"\"$ <\/p>\n

5<\/b><\/strong>\u30012-\u56db\u6c22\u8418\u916e<\/b><\/strong><\/span><\/p>\n

\u00a0\u00a0\u00a0\u00a0\u00a0\u00a02-\u56db\u6c22\u8418\u916e\u4e3b\u8981\u7528\u4e8e\u533b\u836f\u548c\u6db2\u6676\u5de5\u4e1a,\u8fd1\u5e74\u6765\u56fd\u5185\u5916\u9700\u6c42\u5f3a\u52b2,\u5e38\u89c4\u5408\u6210\u8def\u7ebf\u662f\u4ee5\u53d6\u4ee3\u4e3a\u539f\u6599,\u5148\u4e0e\u6c2f\u5316\u4e9a\u781c\u4f5c\u7528\u751f\u6210\u9170\u6c2f,\u9170\u6c2f\u4e0e\u70ef\u8fdb\u884c\u9170\u5316\u53cd\u5e94\u548c\u73af\u5408\u5408\u62102-\u56db\u6c22\u8418\u916e,\u8be5\u6cd5\u5b58\u5728\u7740\u4e0d\u7ecf\u6d4e\u548c\u6eb6\u5242\u4e0d\u6613\u56de\u6536\u7b49\u7f3a\u70b9;\u8fd1\u56fd\u5185\u5f00\u53d1\u51fa\u65b0\u578b\u4e00\u9505\u6cd5\u9170\u5316\u53cd\u5e94,\u91c7\u7528\u4e09\u6c1f\u9150\/\u78f7\u9178\u50ac\u5316\u4f53\u7cfb,\u7531\u53d6\u4ee3\u4e0e\u4e59\u70ef\u8fdb\u884c\u53cd\u5e94,\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u4e09\u6c1f\u53ef\u4ee5\u88ab\u8f6c\u5316\u6210\u4e09\u6c1f\u9150\u76f4\u63a5\u5faa\u73af\u4f7f\u7528,\u4e14\u5bf9\u8bbe\u5907\u8150\u8680\u6027\u8f83\u5c0f,\u975e\u5e38\u5177\u6709\u5e94\u7528\u524d\u666f.<\/span><\/p>\n

6<\/b><\/strong>\u3001N-\u82c4\u57fa-N-\u7532\u57fa\u80fa<\/b><\/strong><\/span><\/p>\n

CAS<\/span><\/td>\n	101-98-4<\/span><\/td>\n	\u5316\u5b66\u5f0f<\/span><\/td>\n	C10H16NO<\/span><\/td>\n<\/tr>\n
EINECS<\/span><\/td>\n	202-994-3<\/span><\/td>\n	\u5206\u5b50\u91cf<\/span><\/td>\n	166.24<\/span><\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n <\/p>\n","protected":false},"excerpt":{"rendered":" \u51e0\u4e2a\u91cd\u8981\u836f\u7269\u4e2d\u95f4\u4f53\u7684\u5e02\u573a\u524d\u666f\u5206\u6790 \u533b\u836f\u4f5c\u4e3a\u7cbe\u7ec6\u5316\u5de5\u9886\u57df\u4e2d\u91cd\u8981\u5730\u884c\u4e1a,\u6210\u4e3a\u8fd1\u5341\u5e74\u6765\u53d1\u5c55\u4e0e\u7ade\u4e89\u5730\u7126\u70b9,\u968f\u7740\u79d1\u5b66\u6280\u672f\u5730\u8fdb\u6b65,\u8bb8\u591a\u533b\u836f\u88ab\u6e90\u6e90\u4e0d\u65ad\u5730\u5f00\u53d1\u51fa\u6765,\u9020\u798f\u4eba\u7c7b,\u8fd9\u4e9b\u533b\u836f\u5730\u5408\u6210\u4f9d\u8d56\u4e8e\u65b0\u578b\u5730\u9ad8\u8d28\u91cf\u5730\u533b\u836f\u4e2d\u95f4\u4f53\u5730\u751f\u4ea7,\u65b0\u836f\u53d7\u5230\u4e13\u5229\u4fdd\u62a4,\u800c\u4e0e\u4e4b\u914d\u5957\u5730\u4e2d\u95f4\u4f53\u5374\u4e0d\u5b58\u5728\u90a3\u6837\u5730\u95ee\u9898,\u56e0\u6b64\u65b0\u578b\u533b\u836f\u4e2d\u95f4\u4f53\u56fd\u5185\u5916\u5e02\u573a\u548c\u5e94\u7528\u524d\u666f\u90fd\u5341\u5206\u770b\u597d.\u65b0\u578b …<\/p>\n","protected":false},"author":1,"featured_media":4926,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[4],"tags":[1412],"_links":{"self":[{"href":"https:\/\/www.51dmea.cn\/wp-json\/wp\/v2\/posts\/4925"}],"collection":[{"href":"https:\/\/www.51dmea.cn\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.51dmea.cn\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.51dmea.cn\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.51dmea.cn\/wp-json\/wp\/v2\/comments?post=4925"}],"version-history":[{"count":2,"href":"https:\/\/www.51dmea.cn\/wp-json\/wp\/v2\/posts\/4925\/revisions"}],"predecessor-version":[{"id":4929,"href":"https:\/\/www.51dmea.cn\/wp-json\/wp\/v2\/posts\/4925\/revisions\/4929"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.51dmea.cn\/wp-json\/wp\/v2\/media\/4926"}],"wp:attachment":[{"href":"https:\/\/www.51dmea.cn\/wp-json\/wp\/v2\/media?parent=4925"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.51dmea.cn\/wp-json\/wp\/v2\/categories?post=4925"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.51dmea.cn\/wp-json\/wp\/v2\/tags?post=4925"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}