\u5bc6\u5ea6<\/td>\n | \u7ea61.2 g\/cm\u00b3<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n4. \u5316\u5b66\u6027\u8d28<\/strong><\/h3>\nDBU\u915a\u76d0\u4ee5\u5176\u5f3a\u78b1\u6027\u548c\u826f\u597d\u7684\u70ed\u7a33\u5b9a\u6027\u8457\u79f0\u3002\u5b83\u7684pKa\u503c\u7ea6\u4e3a24\uff08\u5728DMSO\u4e2d\uff09\uff0c\u8868\u660e\u5176\u5728\u6709\u673a\u6eb6\u5242\u4e2d\u8868\u73b0\u51fa\u6781\u9ad8\u7684\u78b1\u6027\u3002\u8fd9\u79cd\u7279\u6027\u4f7f\u5176\u6210\u4e3a\u8bb8\u591a\u6709\u673a\u53cd\u5e94\u7684\u7406\u60f3\u50ac\u5316\u5242\uff0c\u5c24\u5176\u662f\u5728\u4eb2\u6838\u53d6\u4ee3\u53cd\u5e94\u548c\u8131\u8d28\u5b50\u5316\u8fc7\u7a0b\u4e2d\u3002<\/p>\n \n\u4e8c\u3001DBU\u915a\u76d0\u7684\u5316\u5b66\u7279\u6027\u5206\u6790<\/strong><\/h2>\n1. \u5f3a\u78b1\u6027\u4e0e\u7a33\u5b9a\u6027<\/strong><\/h3>\nDBU\u915a\u76d0\u7684\u5f3a\u78b1\u6027\u6765\u6e90\u4e8e\u5176\u79bb\u5b50\u7ed3\u6784\u3002\u7531\u4e8eDBU\u90e8\u5206\u63d0\u4f9b\u4e86\u5f3a\u5927\u7684\u7535\u5b50\u4f9b\u4f53\u80fd\u529b\uff0c\u800c\u915a\u9634\u79bb\u5b50\u5219\u8fdb\u4e00\u6b65\u589e\u5f3a\u4e86\u5176\u78b1\u6027\u3002\u6b64\u5916\uff0c\u8be5\u5316\u5408\u7269\u5728\u9ad8\u6e29\u4e0b\u8868\u73b0\u51fa\u826f\u597d\u7684\u70ed\u7a33\u5b9a\u6027\uff0c\u8fd9\u4f7f\u5f97\u5b83\u80fd\u591f\u5728\u82db\u523b\u6761\u4ef6\u4e0b\u4fdd\u6301\u6d3b\u6027\u3002<\/p>\n 2. \u50ac\u5316\u673a\u5236<\/strong><\/h3>\nDBU\u915a\u76d0\u7684\u50ac\u5316\u4f5c\u7528\u4e3b\u8981\u4f9d\u8d56\u4e8e\u5176\u4eb2\u6838\u6027\u3002\u5728\u53cd\u5e94\u4e2d\uff0c\u5b83\u53ef\u4ee5\u901a\u8fc7\u4ee5\u4e0b\u6b65\u9aa4\u53d1\u6325\u4f5c\u7528\uff1a<\/p>\n \n- \u8131\u8d28\u5b50\u5316<\/strong>\uff1aDBU\u915a\u76d0\u80fd\u591f\u5feb\u901f\u593a\u53d6\u5e95\u7269\u4e2d\u7684\u8d28\u5b50\uff0c\u751f\u6210\u9ad8\u6d3b\u6027\u7684\u4e2d\u95f4\u4f53\u3002<\/li>\n
- \u7a33\u5b9a\u8fc7\u6e21\u6001<\/strong>\uff1a\u901a\u8fc7\u4e0e\u8fc7\u6e21\u6001\u5f62\u6210\u6c22\u952e\u6216\u9759\u7535\u76f8\u4e92\u4f5c\u7528\uff0c\u964d\u4f4e\u53cd\u5e94\u6d3b\u5316\u80fd\u3002<\/li>\n
- \u4fc3\u8fdb\u4ea7\u7269\u91ca\u653e<\/strong>\uff1a\u5728\u53cd\u5e94\u5b8c\u6210\u540e\uff0cDBU\u915a\u76d0\u4f1a\u91cd\u65b0\u6062\u590d\u5230\u521d\u59cb\u72b6\u6001\uff0c\u7ee7\u7eed\u53c2\u4e0e\u4e0b\u4e00\u8f6e\u50ac\u5316\u5faa\u73af\u3002<\/li>\n<\/ol>\n
\u8fd9\u79cd\u9ad8\u6548\u4e14\u53ef\u91cd\u590d\u5229\u7528\u7684\u50ac\u5316\u673a\u5236\uff0c\u4f7f\u5176\u6210\u4e3a\u8bb8\u591a\u5de5\u4e1a\u53cd\u5e94\u7684\u7406\u60f3\u9009\u62e9\u3002<\/p>\n 3. \u53cd\u5e94\u7c7b\u578b\u4e0e\u9002\u7528\u8303\u56f4<\/strong><\/h3>\nDBU\u915a\u76d0\u5e7f\u6cdb\u5e94\u7528\u4e8e\u4ee5\u4e0b\u51e0\u7c7b\u53cd\u5e94\uff1a<\/p>\n \n- Michael\u52a0\u6210\u53cd\u5e94<\/strong>\uff1a\u7528\u4e8e\u5408\u6210\u03b2-\u916e\u916f\u548c\u5176\u4ed6\u529f\u80fd\u6027\u5316\u5408\u7269\u3002<\/li>\n
- \u73af\u52a0\u6210\u53cd\u5e94<\/strong>\uff1a\u5982Diels-Alder\u53cd\u5e94\u7684\u8f85\u52a9\u50ac\u5316\u5242\u3002<\/li>\n
- \u7f29\u5408\u53cd\u5e94<\/strong>\uff1a\u4f8b\u5982Knoevenagel\u7f29\u5408\u53cd\u5e94\u3002<\/li>\n
- \u916f\u4ea4\u6362\u53cd\u5e94<\/strong>\uff1a\u5728\u805a\u5408\u7269\u6539\u6027\u4e2d\u8d77\u5230\u5173\u952e\u4f5c\u7528\u3002<\/li>\n<\/ul>\n
\n\u4e09\u3001DBU\u915a\u76d0\u7684\u5e94\u7528\u9886\u57df<\/strong><\/h2>\nDBU\u915a\u76d0\u56e0\u5176\u51fa\u8272\u7684\u5316\u5b66\u7279\u6027\u548c\u591a\u529f\u80fd\u6027\uff0c\u5728\u591a\u4e2a\u9886\u57df\u5c55\u73b0\u51fa\u5de8\u5927\u7684\u5e94\u7528\u6f5c\u529b\u3002\u4ee5\u4e0b\u662f\u51e0\u4e2a\u5178\u578b\u7684\u5e94\u7528\u573a\u666f\uff1a<\/p>\n 1. \u6750\u6599\u79d1\u5b66\u4e2d\u7684\u5e94\u7528<\/strong><\/h3>\n\u5728\u6750\u6599\u79d1\u5b66\u9886\u57df\uff0cDBU\u915a\u76d0\u5e38\u88ab\u7528\u4f5c\u805a\u5408\u7269\u5408\u6210\u7684\u50ac\u5316\u5242\u3002\u4f8b\u5982\uff0c\u5728\u805a\u6c28\u916f\u6ce1\u6cab\u7684\u751f\u4ea7\u8fc7\u7a0b\u4e2d\uff0c\u5b83\u53ef\u4ee5\u6709\u6548\u4fc3\u8fdb\u5f02\u6c30\u9178\u916f\u4e0e\u591a\u5143\u9187\u4e4b\u95f4\u7684\u53cd\u5e94\uff0c\u4ece\u800c\u63d0\u9ad8\u4ea7\u54c1\u7684\u673a\u68b0\u6027\u80fd\u548c\u8010\u70ed\u6027\u3002<\/p>\n\n\n\n\n\n\n\n \u5e94\u7528\u573a\u666f<\/th>\n | \u4f18\u52bf\u7279\u70b9<\/th>\n<\/tr>\n<\/thead>\n |
---|
\u805a\u6c28\u916f\u6ce1\u6cab<\/td>\n | \u63d0\u9ad8\u53cd\u5e94\u901f\u7387\uff0c\u6539\u5584\u4ea7\u54c1\u6027\u80fd<\/td>\n<\/tr>\n | \u73af\u6c27\u6811\u8102\u56fa\u5316<\/td>\n | \u52a0\u901f\u56fa\u5316\u8fc7\u7a0b\uff0c\u589e\u5f3a\u6750\u6599\u97e7\u6027<\/td>\n<\/tr>\n | \u9ad8\u6027\u80fd\u6d82\u6599<\/td>\n | \u6539\u5584\u6d82\u5c42\u9644\u7740\u529b\u548c\u8010\u5019\u6027<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n2. \u533b\u836f\u7814\u53d1\u4e2d\u7684\u5e94\u7528<\/strong><\/h3>\n\u5728\u533b\u836f\u7814\u53d1\u9886\u57df\uff0cDBU\u915a\u76d0\u662f\u8bb8\u591a\u836f\u7269\u4e2d\u95f4\u4f53\u5408\u6210\u7684\u91cd\u8981\u5de5\u5177\u3002\u4f8b\u5982\uff0c\u5b83\u53ef\u7528\u4e8e\u5236\u5907\u6297\u80bf\u7624\u836f\u7269\u7684\u5173\u952e\u7247\u6bb5\uff0c\u6216\u8005\u5728\u624b\u6027\u5316\u5408\u7269\u7684\u4e0d\u5bf9\u79f0\u5408\u6210\u4e2d\u53d1\u6325\u91cd\u8981\u4f5c\u7528\u3002<\/p>\n 3. \u73af\u5883\u6cbb\u7406\u4e2d\u7684\u5e94\u7528<\/strong><\/h3>\n\u8fd1\u5e74\u6765\uff0cDBU\u915a\u76d0\u5728\u73af\u5883\u6cbb\u7406\u65b9\u9762\u7684\u5e94\u7528\u9010\u6e10\u53d7\u5230\u5173\u6ce8\u3002\u4f8b\u5982\uff0c\u5b83\u53ef\u4ee5\u4f5c\u4e3a\u50ac\u5316\u5242\uff0c\u7528\u4e8e\u5e9f\u6c34\u5904\u7406\u4e2d\u7684\u6709\u673a\u6c61\u67d3\u7269\u964d\u89e3\u3002\u901a\u8fc7\u4fc3\u8fdb\u6c27\u5316\u53cd\u5e94\uff0cDBU\u915a\u76d0\u80fd\u591f\u663e\u8457\u63d0\u9ad8\u6c61\u67d3\u7269\u7684\u53bb\u9664\u6548\u7387\u3002<\/p>\n\n\n\n\n\n\n\n \u6c61\u67d3\u7269\u7c7b\u578b<\/th>\n | \u964d\u89e3\u6548\u7387\u63d0\u5347\u767e\u5206\u6bd4\uff08%\uff09<\/th>\n<\/tr>\n<\/thead>\n |
---|
\u7cfb\u7269<\/td>\n | +30~40<\/td>\n<\/tr>\n | \u519c\u836f\u6b8b\u7559<\/td>\n | +20~30<\/td>\n<\/tr>\n | \u91cd\u91d1\u5c5e\u87af\u5408<\/td>\n | +15~25<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n4. \u65e5\u5316\u4ea7\u54c1\u4e2d\u7684\u5e94\u7528<\/strong><\/h3>\n\u5728\u65e5\u5316\u4ea7\u54c1\u9886\u57df\uff0cDBU\u915a\u76d0\u53ef\u4ee5\u7528\u4f5c\u9999\u7cbe\u9999\u6599\u7684\u5408\u6210\u50ac\u5316\u5242\u3002\u4f8b\u5982\uff0c\u5728\u67d0\u4e9b\u5929\u7136\u7cbe\u6cb9\u7684\u63d0\u53d6\u548c\u7eaf\u5316\u8fc7\u7a0b\u4e2d\uff0c\u5b83\u80fd\u591f\u663e\u8457\u63d0\u9ad8\u6536\u7387\u548c\u4ea7\u54c1\u8d28\u91cf\u3002<\/p>\n \n |
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